Microsoft word - all acrylic polymer powders_eng120
MATERIAL SAFETY DATA SHEET
Page 1 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
1. PRODUCT IDENTIFICATION
ALL ACRYLIC POLYMER POWDERS - All Shades
ACRYLATES COPOLYMER POWDER
PROFESSIONAL OR SUNDRY USE ONLY
1.6 Manufacturer's
Generic MSDS for Training Purposes Only
An toàn sản phẩm chung chung chỉ cho mục đích đào tạo
1.7 Manufacturer's
This document has been prepared by the Nail Manufacturers Council for training purposes only. The document is not intended to
represent any particular product or company. Please consult the manufacturer for the MSDS of any product you are using.
Tài liệu này đã được chuẩn bị bởi Nail Hội đồng các nhà sản xuất chỉ cho mục đích đào tạo. Tài liệu này không có ý định để đại diện
cho bất kỳ sản phẩm cụ thể hoặc công ty. Xin vui lòng tham khảo ý kiến các nhà sản xuất trong Bản Thông số an toàn của bất kỳ sản
phẩm bạn đang sử dụng.
CHEMTREC: +1 (703) 527-3887 / +1 (800) 424-9300
2. HAZARD IDENTIFICATION
This product is not classified as a HAZARDOUS SUBSTANCE or as DANGEROUS GOODS according to the classification criteria of
NOHSC:1008 (2004) and ADG Code (Australia). Allergic contact dermatitis is possible with prolonged or repeated contact. The
product is a fine powder, and may cause a slipping and falling hazard if spilled.
Routes of Entry:
NO Ingestion:
Effects of Exposure:
EYES:
Possible irritation from dust.
Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION:
No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
Symptoms of Overexposure:
Symptoms of skin overexposure may include redness, itching, and irritation of affected areas. Overexposure in eyes may cause
redness, itching and watering. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) upon prolonged or
repeated exposure.
Acute Health Effects:
Moderate irritation to eyes and skin near affected areas. Additionally, high concentrations of vapors can cause drowsiness, dizziness,
headaches and nausea.
Chronic Health Effects:
No long-term health effects are known.
Eyes, skin & respiratory system.
NA = Not Available; ND = Not Determined; NE = Not Established; NF = Not Found; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
MATERIAL SAFETY DATA SHEET
Page 2 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
3. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH NOHSC
CHEMICAL NAME(S)
RTECS No.
EINECS No.
TLV STEL TWA STEL PEAK PEL STEL IDLH
ACRYLATES COPOLYMER
25133-97-5 NA
POLYETHYLMETHACRYLATE
9003-42-3 NA
0-50 NA NA NF NF NF NA NA NA
POLYMETHYL METHACRYLATE
9011-14-7 NA
0-50 NA NA NF NF NF NA NA NA
BENZOYL PEROXIDE
DM8575000 202-327-6
SILICA 7631-86-9
EU8655000
231-545-4
3000 RESP
MAY ALSO CONTAIN:
MICA 12001-26-2
VV8760000
310-127-6
0-2 NA NA NF NF NF NA NA
25038-59-9 NA
0-2 NA NA NF NF NF NA NA
TEREPHTHALATE
POLYBUTYLENE
NA NA NA 0-2
NA NA NF NF NF NA NA NA
ETHYLENE/VA COPOLYMER
24937-78-8
NA NA NF NF NF NA NA NA
POLYESTER-3 NA
NA NA NF NF NF NA NA NA
CI 77000 (ALUMINUM POWDER)
7429-90-5
BD0330000
231-072-3
0-2 NA NA NF NF NF NA NA
CI 77891 (TITANIUM DIOXIDE)
13463-67-7
XR2275000
236-675-5
0-2 (10) NA NF NF NF (15) NA NA
CI 77510 (FERRIC
14038-43-8 LJ8200000 237-875-5
0-2 NA NA NF NF NF NA NA
CI 47005 (YELLOW 10)
8003-22-3
232-318-2
0-2 NA NA NF NF NF NA NA NA
CI 77491 (RED IRON OXIDE)
1309-37-1 NO7400000
215-168-2 0-2
NA NA NF NF NF NA NA NA
CI 77492 (YELLOW IRON OXIDE)
1332-37-2
NO7380000 215-570-8
NA NA NF NF NF NA NA NA
CI 77499 (BLACK IRON OXIDE)
1309-37-1 NO7400000
215-168-2 0-2
NA NA NF NF NF NA NA NA
CI 77163 (BISMUTH
7787-59-9 NA
232-122-7 0-2
NA NA NF NF NF NA NA NA
CI 15850 (RED 6 / RED 7)
5281-04-9
QJ1975000
226-109-5
NA NA NF NF NF NA NA NA
CI 45410 (RED 27 / RED 28)
18472-87-2
LM5900000
242-355-6
NA NA NF NF NF NA NA NA
CI 73360 (RED 30)
2379-74-0
219-163-6
NA NA NF NF NF NA NA NA
CI 77120 (BARIUM SULFATE)
7727-43-7
CR0600000
231-784-4
0-2 NA NA NF NF NF NA NA
CI 42090 (BLUE 1)
2650-18-2
220-168-0
NA NA NF NF NF NA NA NA
CI 15985 (YELLOW 6)
2783-94-0
QK4725000 220-491-7
NA NA NF NF NF NA NA NA
CI 77742 (MANGANESE VIOLET)
10101-66-3
233-257-4
NA NA NF NF NF NA NA NA
CI 77007 (ULTRAMARINE BLUE)
1302-83-6
215-111-1
NA NA NF NF NF NA NA NA
CI 47000 (YELLOW 11)
8003-22-3
GE5925000
232-318-2
0-2 NA NA NF NF NF NA NA
CI 45380 (RED 21 / RED 22)
15086-94-9
239-138-3
NA NA NF NF NF NA NA NA
MATERIAL SAFETY DATA SHEET
Page 3 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
4. FIRST AID MEASURES
INGESTION:
If ingested, do not induce vomiting! If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the
patient is vomiting, continue to offer water or milk. Never give water or milk to an unconscious person. Contact the
nearest Poison Control Center or local emergency number. Provide an estimate of the time at which the material was
ingested and the amount of the substance that was swallowed.
If irritation occurs & product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of the
affected area with plenty of soap and water. Remove contaminated clothing and wash thoroughly before reuse. If
irritation, redness or swelling persists, consult a physician immediately.
If product gets in the eyes, flush with copious amounts of lukewarm water for at least 15 minutes. Open and close
eyelid(s) to ensure thorough irrigation. If irritation persists seek immediate medical attention.
INHALATION: Remove victim to fresh air at once. If breathing stops, perform artificial respiration. Seek immediate medical attention.
Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis, other skin conditions, and disorders of the target organs (eyes,
skin, respiratory system). Preclude from exposure those individuals that are FLAMMABILITY
susceptible to dermatitis, asthma or bronchitis.
REACTIVITY 1
PROTECTIVE EQUIPMENT B
EYES SKIN
5. FIREFIGHTING MEASURES
Flashpoint & Method:
264 °C (508 °F), TCC
5.2 Autoignition
5.3 Flammability
Lower Explosive Limit (LEL):
Upper Explosive Limit (UEL):
Fire & Explosion Hazards:
Keep away from excessive heat, open flames, sparks, and other possible sources of ignition.
5.5 Extinguishing
Carbon dioxide, dry chemical & water spray.
5.6 Firefighting
Keep containers cool until well after the fire is out. Prevent runoff from fire control or dilution from entering
sewers, drains, drinking water supply, or any natural waterway. Firefighters should wear full face, self-
contained breathing apparatus (MSHA/NIOSH approved or the equivalent) and impervious protective
clothing.
6. ACCIDENTAL RELEASE MEASURES
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., < 5 lbs) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open doors
and windows) and secure all sources of ignition. Carefully sweep up spilled material and place into appropriate closed container(s) for
disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas and outside of container
with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before reuse.
For spills ≥ 5 lbs, deny entry to all unprotected individuals. Contain spill with inert material (e.g., sand or earth). Carefully sweep up
spilled material and place into appropriate closed container(s) for disposal. Remove contaminated clothing promptly and wash
affected skin areas with soap and water. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.
MATERIAL SAFETY DATA SHEET
Page 4 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
7. HANDLING & STORAGE INFORMATION
Work & Hygiene Practices:
Avoid prolonged contact with this material. Limit inhalation of the vapors generated by this product. Use in a well-ventilated location
(e.g., local exhaust ventilation, fans). Wash exposed skin thoroughly with plenty of soap & water after using this product. Do not eat,
drink, or smoke while handling this product.
Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Keep away from incompatible materials listed in Section 10. Do not store in
damaged or unmarked containers or storage devices. Keep containers securely closed when not in use. Open slowly on a level,
stable surface. Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with
care. Keep away from children at all times!
Local exhaust ventilation is recommended.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
Ventilation & Engineering Controls:
Use with adequate ventilation (e.g., local exhaust ventilation, fans). Ensure appropriate decontamination equipment is available (e.g.,
sink, safety shower, eye-wash station).
No special respiratory protection is required under typical circumstances of use or handling. In instances where vapors or sprays of this
product are generated, and respiratory protection is needed, use only protection authorized by 29 CFR §1910.134, applicable U.S. State
regulations, or the Canadian CAS Standard Z94.4-93 and applicable standards of Canadian Provinces, EC member States, or Australia.
Avoid eye contact. None required under normal conditions of use. However, may cause irritation in some sensitive individuals. When
handling large quantities (e.g., ≥ 1 gallon), safety glasses with side shields should be used.
No apron required when handling small quantities.
When handling large quantities (e.g., ≥ 1 gallon), eye wash stations and deluge showers should be available. Upon completion of work
activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
No apron required when handling small quantities.
When handling large quantities (e.g., ≥ 1 gallon), eye wash stations and deluge showers should be available. Upon completion of work
activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
9. PHYSICAL & CHEMICAL PROPERTIES
Appearance & Color:
Clear or colored free flowing powder, mild acrylic odor
Insoluble in water.
MATERIAL SAFETY DATA SHEET
Page 5 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
10. STABILITY & REACTIVITY
Relatively stable under ambient conditions when stored properly.
Hazardous Decomposition Products:
If exposed to extremely high temperatures, products of thermal decomposition may include irritating vapors and toxic gases (e.g.,
oxides of carbon & nitrogen).
Will not occur.
Exposure or contact to extreme temperatures, incompatible chemicals, strong light sources, sparks, flame.
10.5 Incompatible
Strong oxides, peroxides or strong acids.
11. TOXICOLOGICAL INFORMATION
This product has not been tested on animals to obtain toxicological data. There are toxicology data for the components of this
product, which are found in the scientific literature. These data have not been presented in this document.
See Section 2.5
No long-term health effects are known.
11.5 Reproductive
This product is not reported to produce reproductive toxicity in humans.
This product is not reported to produce mutagenic effects in humans.
Embryotoxicity:
This product is not reported to produce embryotoxic effects in humans.
Teratogenicity:
This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity:
This product is not reported to produce reproductive effects in humans.
Irritancy of Product:
See Section 2.3
Recommendations:
Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental
This product will slowly volatile from soil. Components of this product will slowly decompose into organic compounds.
Effects on Plants & Animals:
There is no specific data available for this product.
Effects on Aquatic Life:
There is no specific data available for this product. However, releases of large volumes may be harmful or fatal to overexposed
aquatic life. Aquatic toxicity data for components of this product are available, but are not presented in this MSDS.
MATERIAL SAFETY DATA SHEET
Page 6 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
13. DISPOSAL CONSIDERATIONS
Dispose in accordance with local, state and Federal hazardous waste laws.
14. TRANSPORTATION INFORMATION
The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG, SCT, ADGR and the CTDGR. 14.1 49
NOT REGULATED
NOT REGULATED
NOT REGULATED
NOT REGULATED
NOT REGULATED
NOT REGULATED
NOT REGULATED
15. REGULATORY INFORMATION
SARA Reporting Requirements:
NA
SARA Threshold Planning Quantity:
NA
All components of this product are listed in the TSCA Inventory or are exempt.
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List. Class B2 Flammable Liquid.
Ingredients in this mixture on found on the following state criteria lists:
California OSHA Hazardous Substances List
Benzoyl Peroxide, Titanium dioxide, Silica
Delaware Air Quality Management List
Benzoyl Peroxide
Massachusetts Hazardous Substances List
Benzoyl Peroxide, Silica
Minnesota Hazardous Substances List
Benzoyl Peroxide, Silica
New Jersey Right to Know Hazardous Substances List
Benzoyl Peroxide, Silica
Pennsylvania Hazardous Substances List
Benzoyl Peroxide, silica
Wisconsin Hazardous Substances List
Benzoyl Peroxide
67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC.
MATERIAL SAFETY DATA SHEET
Page 7 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
16. OTHER INFORMATION
Precisely follow directions and MSDS (available through your supplier) for use. Avoid skin contact. If redness or other signs of adverse
reaction occur, discontinue use immediately. Use only in a wel ventilated area. A ventilation system that expels vapors to the
outdoors is recommended. Keep out of reach of children. In case of emergency, contact your physician or local Poison Control
Center immediately. FOR PROFESSIONAL USE ONLY!
Terms & Definitions:
Please see last page of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR §1910.1200. Other government regulations must be reviewed for applicability to this product. To the best of ShipMate's knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein relates only to the specific product(s). If this product(s) is combined with other materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.
This document has been prepared by the Nail Manufacturers Council for training purposes
Generic MSDS for Training Purposes
only. The document is not intended to represent any particular product or company. Please
consult the manufacturer for the MSDS of any product you are using.
An toàn sản phẩm chung chung chỉ
Tài liệu này đã được chuẩn bị bởi Nail Hội đồng các nhà sản xuất chỉ cho mục đích đào tạo.
cho mục đích đào tạo
Tài liệu này không có ý định để đại diện cho bất kỳ sản phẩm cụ thể hoặc công ty. Xin vui
lòng tham khảo ý kiến các nhà sản xuất trong Bản Thông số an toàn của bất kỳ sản phẩm
bạn đang sử dụng.
ShipMate, Inc.
PO Box 787
Sisters, OR 97759-0787 USA
Phone: +1 (310) 370-3600
Fax: +1 (310) 370-5700
e-mail: [email protected]
MATERIAL SAFETY DATA SHEET
Page 8 of 8
MSDS-120
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS & 2001/58 EC Standards
MSDS Revision: 1.0
MSDS Revision Date: 06/14/2010
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
Chemical Abstract Service Number
FLAMMABILITY LIMITS IN AIR:
EXPOSURE LIMITS IN AIR:
Minimum temperature required to initiate combustion
American Conference on Governmental Industrial Hygienists
Temperature
in air with no other source of ignition
Threshold Limit Value
Lower Explosive Limit - lowest percent of vapor in air, by
U.S. Occupational Safety and Health Administration
volume, that will explode or ignite in the presence of
Permissible Exposure Limit
an ignition source
Immediately Dangerous to Life and Health
Upper Explosive Limit - highest percent of vapor in air,
by volume, that will explode or ignite in the presence of
FIRST AID MEASURES:
an ignition source
CPR Cardiopulmonary resuscitation - method in which a person
HAZARD RATINGS:
whose heart has stopped receives manual chest
compressions and breathing to circulate blood and provide oxygen to the body.
HAZARDOUS MATERIALS IDENTIFICATION
SYSTEM: HMIS
REACTIVITY
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
PRECAUTIONS
PERSONAL PROTECTION
NCCHL44T NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
TOXICOLOGICAL INFORMATION:
PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
Lethal concentration (gases) which kills 50% of the
Concentration expressed in parts of material per million parts
Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
TC, TCo, LClo, & LCo
International Agency for Research on Cancer
National Toxicology Program
Registry of Toxic Effects of Chemical Substances
Bioconcentration Factor
X Consult your supervisor or S.O.P. for
special handling directions.
Median threshold limit
log KOW or log KOC
Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
Face Shield &
Safety Glasses
Splash Goggles
Eye Protection
WHMIS Canadian Workplace Hazardous Material Information System
U.S. Department of Transportation
Transport Canada
Synthetic Apron
Full Suit
Dust Respirator
U.S. Environmental Protection Agency
Canadian Domestic Substance List
Canadian Non-Domestic Substance List
Dust & Vapor
Full Face
Airline Hood/Mask
Vapor Respirator
Respirator
Respirator
Canadian Priority Substances List
U.S. Toxic Substance Control Act
Note: the dotted circle indicates that this respiratory protective
European Union (European Union Directive 67/548/EEC)
equipment is required for high concentrations or for large
volume spills or releases of product.
EC INFORMATION:
OTHER STANDARD ABBREVIATIONS:
C E F N O T+ Xi Xn
Self-Contained Breathing Apparatus
Corrosive Explosive Flammable
Harmful Oxidizing Toxic
Irritant Harmful
Source: http://www.hazwastehelp.net/publications/eDownload.aspx?DocID=EqHz%2FKDmmnY%3D
Summary Plan Description Construction Industry Laborers Welfare Fund To All Participants: We are pleased to provide you with the Construction Industry Laborers Welfare Fund benefits booklet. This booklet summarizes the benefits available to you under your Welfare Plan. The contents and provisions of the Plan as of January 1, 2014, include a description of your medical, dental, vision, loss of time, death, and accidental death and dismemberment benefits. This booklet includes eligibility rules, description of the benefits available, as well as limitations and exclusions. Benefit amounts are summarized on the Schedule of Benefits. This booklet also contains information concerning your rights as a participant under the Plan and your rights to continue coverage after it has been cancelled. The Employee Retirement Income Security Act of 1974 (ERISA) requires that certain information be provided to participants. That information is included here, as well. There is a separate Plan Document which describes in more detail your eligibility to participate and the benefits you will receive under the Plan. Only the Trustees are authorized to interpret the Plan and not any Employer or Union representative. This Plan Document is available at the Fund Office for your review. You and your Dependents should read this booklet carefully and retain it in a safe place for future reference. If you should have any questions concerning the benefit program, please feel free to write or call the Fund Office at (800) 392-8726. The Welfare Fund is maintained and administered by an unpaid Board of Trustees on which the Union and Employers are equally represented. The Board of Trustees has the primary responsibility for decisions regarding eligibility rules, time and manner of payment of benefits, administrative policies, management of Fund assets, and interpretation of Plan provisions. If you wish to contact the Board of Trustees, write the Fund Administrator at the Fund Office. Construction Industry Laborers Welfare Fund
"Market versus technology drive in R&D internationalization: four different patterns of managing research and development" By: Maximilian von Zedtwitz and Oliver Gassmann Luis Ojeda Ricalde R&D in Multinationals ULB - Solvay Business School Luis Ojeda Ricalde List of Abbreviations Section 1: Article 1 Trends in R&D Internationalization 1.1 Main Research and Development Centers of the World