Hich 7730 benzoyl peroxide hardener for light weight filler

August 2015
Safety Data Sheet
Page 1 of 7
BENZOYL PEROXIDE HARDENER

HiChem Paint Technologies Pty.Ltd.
A.B.N. 95 064 139 653
73 Hallam South Road, HALLAM, VICTORIA 3803.
Telephone : {03} 9796 3400
Facsimile : {03} 9796 4500 www:hichem.com.au If poisoning occurs, consult with the Poisons Information Centre {Telephone 13 11 26}.
Emergency Telephone Number (Police, Fire or Ambulance) : 000

HAZARD IDENTIFICATION
The product is classified as Hazardous Substance in accordance with SAFE WORK Australia – Hazardous Substances Information System {HSIS 2013} AUSTRALIA, Global Harmonised System {GHS} and Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP). GHS HAZARDOUS STATEMENTS
Heating may cause a fire or explosion. Combustible Liquid – Flash Point > 150º Celsius Boiling Point – ≥ 150 º Celsius May be harmful if swallowed, in contact with skin and if Causes skin irritation, eyes and respiratory tract Repeated exposure may cause skin dryness or cracking. May cause dizziness or drowsiness May damage fertility or the unborn child May cause damage to organs. Very Toxic effects to aquatic life. GHS PRECAUTIONARY STATEMENTS
STATEMENT PRECAUTIONARY
PRECAUTIONARY STATEMENT TEXT
STATEMENT CODE
Seek medical advice if required. Keep out of reach of children. Carefully read and understand this document during application and handling period. Keep in original container and tightly closed in a cool dry place with plenty of ventilation when not in use. Ensure all equipment and lighting is explosion proof during application and handling period. Avoid breathing vapours during the manufacturing and handling period. Wear protective clothing, hair, eye and skin protection, safety footwear and organic vapour – particulate respirator, at all times. Do not enter into confined areas and ensure there is adequate ventilation Do not smoke, eat or drink during manufacturing and handling period Ensure there is adequate ventilation at all times away from sunlight during the application and handling period. Ensure all protective clothing laundered before reuse. August 2015
Safety Data Sheet
Page 2 of 7
BENZOYL PEROXIDE HARDENER
Avoid release to the environment includes drains, sewage, waterways and atmosphere. If swallowed, rinse the mouth water immediately.
Contact the Poisons Information Centre (Telephone 13
11 26) urgently.
P 302, 303, 313, 362 If on skin or hair, wash all exposed area with plenty of warm water and soap. Seek medical advice if any irritation occurs. Remove all contaminated clothing immediately. If inhaled, removed oneself to fresh air from the contaminated area and keep warm in a comfortable position. Seek medical advice if any symptoms immediately If in eyes, immediately flush with plenty of water. Remove contact lenses if safe to do so if worn. Contact urgent medical advice immediately if any irritation or blurring occurs. If splashed onto clothing, removed all contaminated clothing and wash with plenty of water immediately before reuse If case of fire, use dry sand or earth, or alcohol resistant foam. Containers may explode on heating. If safe to do so, remove all electrical equipment in the direction of fire. Ensure all power supplies are switch off. Consider evacuate the area if the fire is potential risk. Eliminate all ignition sources if safe to do so away from the direction of fire. Collect and absorb all spillages onto dry sand or earth and placed into clean, dry and labelled containers prior to disposal. Store in a cool, well dry and ventilated place in a Flammable Goods Store and away from protect from direct sunlight. Ensure the Hardener is away from its Polyester Base to prevent a fire. Ensure the container(s) are tightly closed and kept in a secured, locked cabinet. The outside of the cabinet must be carefully locked and clearly labelled at all times. Do not recycle the remaining contents. When disposing both emptied container(s) and residues it is important to display the Flammable Diamond on the container(s) prior disposing at approved disposal site.
Product Usage.
BENZOYL PEROXIDE HARDENER is an organic peroxide component for 2 pack polyester filler repair kit. For further information contact HICHEM helpdesk on (03) 9796 3034. August 2015
Safety Data Sheet
Page 3 of 7
BENZOYL PEROXIDE HARDENER
IDENTIFICATION of the SUBSTANCE(S) and COMPOSITION

Product Name
BENZOYL PEROXIDE HARDENER Code BPER
Name
CAS Number
Proportion w/w
Benzoyl Peroxide Di Methyl Phthalate 131 – 11 – 3 FIRST AID MEASURES

Inhalation
If the operator feels drowsy, dizzy, tired or experiencing headaches, remove the victim away from the contaminated area to the fresh air. Keep the victim warm and quiet until all symptoms subside. If the victim is not breathing, apply artificial respiration immediately away from the contaminated area or seek URGENT medical attention. If swallow, and only if the operator is conscious, give water to drink. DO NOT induced vomiting; seek URGENT medical
attention if frothing from the mouth occurs.
Eyes
If splashed into eyes, hold eyelids apart, and flush the eyes continuously with running for at least 15 minutes. Continue flushing until advised by a doctor. Skin and Hair
If skin and hair contact occurs, remove contaminated clothing, and wash thoroughly with soap and plenty of water. Continue flushing until advised by a doctor. First Aid
Clean Water Supply, soap or skin cleaner, barrier cream, emergency showers and eye wash stations. Advice to Doctor
If poisoning occurs, consult with the Poisons Information
Centre {Telephone 13 11 26}. Have a copy of this material
safety data sheet or label available. Treat symptomatically as
symptoms may be delayed for several hours after exposure.
FIRE FIGHTING MEASURES

Extinguishing
Carbon Dioxide {CO2}, alcohol resistant foam, dry Media and
chemical or water spray. DO NOT use water jets. Bund
area with sand to prevent run – off entering waterways, sewage and drains. On heating, containers may rupture and explode: contents may burn rapidly forming toxic gases including carbon monoxide, soot and smoke, above the boiling point Oxidising Combustible Liquid - Boiling Point ≥ 150º Celsius Specific Hazards
Vapours may form explosive/air mixtures when heated. Precautions in
Fire – fighters must wear Chemical Splash Suit with connection with
attached Self – Contained Breathing Apparatus Fire
incorporating an Organic Vapour Respirator and gloves. Evacuate all non fire–fighting personnel away from the area. Turn off all electricity and power supplies. Keep containers cool with water spray or water to prevent rupture or burning. Move away all packages and equipment from the direction of the fire, if safe to do so Keep upwind. August 2015
Safety Data Sheet
Page 4 of 7
BENZOYL PEROXIDE HARDENER
ACCIDENTAL RELEASE MEASURES

Emergency
Contain all spills and leaks. Avoid contamination with spilt material on surfaces or entering waterways, drains and Spills and Leaks
sewage. Remove all sources of ignition and NO SMOKING.
Wear the recommended full body impervious clothing, gloves
and breathing apparatus as per AS– NZ 1715/16. Keep
upwind. Absorb all spilt contents onto sand or earth.
Collect all residues into labelled and sealed containers for disposal via special waste collection services as per local Statutory Authority requirements. Ensure there is adequate ventilation at all times during the cleaning up period. HANDLING and STORAGE

Precautions for
Combustible Liquid. Remove all sources of ignition. Wear the recommended Safe Handling
Personal Protective Equipment including organic vapour respirator, eye/face protection, protective clothing, gloves and enclosed footwear. Ensure there is adequate ventilation at all times. After use, before eating, drinking or smoking, wash all exposed skin and hair with soap and water. EXPOSURE CONTROLS for 8 hours
Di Methyl Phthalate = 15 milligram/cubic metre 14807 – 96 – 6 Benzoyl Peroxide = 5 milligram/cubic metre MAK
PERSONAL PROTECTION

Inhalation
The wearing of Organic Vapour Respirator should be worn
AS –NZS
at all times during the handling period. Eye
The wearing of safety glasses fitted with side shields AS –NZS 1337
should be worn at all times during the handling period. Do
not wear contact lenses.
The wearing of Neoprene or PVC gloves should be worn
AS –NZS 2161
at all times during the handling period. The wearing of enclosed footwear should be worn at all
AS –NZS 2210
times during the handling period. The wearing of anti–static clothing made on natural or AS –NZS 2919
synthetic high temperature fibre should be worn at all
times during the handling period. AS –NZS 1270
Other
Wear safety footwear at all times. Avoid contact with eyes and skin at all times. Avoid inhaling vapours. August 2015
Safety Data Sheet
Page 5 of 7
BENZOYL PEROXIDE HARDENER
PHYSICAL – CHEMICAL PROPERTIES
A colourless liquid with no appreciable odour. pH
Vapour Pressure
(Butyl Acetate = 1)
Boiling Point oC
1.13 {calculated value} Solubility in
water
Flash Point oC
> 150 o C (literature value) Lower Explosive Limit = 1.1 Upper Explosive Limit = 7.5 Limits
Auto Ignition oC
Volatile Organic
0.0 % volume/volume Compounds VOC
Volatile
No known volatile substances. Components

STABILITY and REACTIVITY

Chemical Stability
Stable under normal conditions of use. Conditions to avoid
Avoid contact with heat and all ignition sources. On heating, containers may rupture and explode: contents may burn rapidly forming toxic gases including carbon monoxide, soot and smoke. products
Incompatible
materials
Hazardous Reactions Avoid contact with alcohols and metals
TOXICOLOGICAL INFORMATION
Oral
LC50 (rat)
LD50 (rabbit)
Di Methyl Phthalate Benzoyl Peroxide No data available No data available TOXICOLOGICAL INFORMATION (CONTINUED)

Health Effects – Toxicological and Other Health Information
Inhalation
No data available No data available. If in eyes, may cause other symptoms including burning sensation, redness, swelling and/or blurred vision. Also, may cause decreased in colour perception. May have degreasing effect on the skin may result in contact dermatitis. Repeated or prolonged exposure may cause skin dryness and cracking. Carcinogenic Not carcinogenic in animal studies Mutagenic Not mutagenic in animal studies. May cause congenital malfunction in the foetus.

August 2015
Safety Data Sheet
Page 6 of 7
BENZOYL PEROXIDE HARDENER
ECOLOGICAL INFORMATION

Environment
Very toxic effects to aquatic life. No data available. Degradability
Mobility
No data available DISPOSAL CONSIDERATIONS

Collect all residues and placed into labelled and sealed containers. Do not incinerate empty containers
after use. Dampen all unwanted cloths and rags in water prior to disposal. Do not recycle contents. Crush
all small empty containers. Large containers and drums may be sent to an approved drum recycler. Ensure
all contents do not pollute waterways, drains and sewage


TRANSPORT INFORMATION

UN number
Proper Shipping
POLYESTER HARDENER COMPONENT – immiscible Name
Subsidiary Risk
Packing Group
Initial Emergency
Response Guide
HAZCHEM 3[Y]
IMDG
REGULATORY INFORMATION

Regulatory
The product is classified as Hazardous Substance in accordance to SAFE WORK Information and
AUSTRALIA {HSIS} and Globally Harmonised System as Harmful and Irritant. Hazard Category
SUSMP
Classified as a Schedule S 5 Poison. Classification


August 2015
Safety Data Sheet
Page 7 of 7
BENZOYL PEROXIDE HARDENER
OTHER INFORMATION

Emergency
Poisons Information Centre 13 11 26
HiChem Paint Technologies
(03) 9796 3400
Data provided is to best of HiChem Paint Technologies Proprietary Limited knowledge and believe to be accurate and reliable as of the date of issued. However no expressed or implied warranties are given. HiChem Paint Technologies Proprietary Limited cannot anticipate or control the conditions under which this information may be used. Therefore, it is user's responsibility to satisfy themselves as to the suitability and completeness of such information for their particular use. It is the responsibility of the user to ensure that the issue is current. This information given is a non-controlled document Version 2.0 HICH 7730 August 2015

Source: http://www.hichem.com.au/hicheminfo/WEB_MSDS/H.PDF